I know this thread was started several months ago, but I might as well reply in case anyone else is interested. I also always wondered how this effect was achieved, and I finally (sort of) figured it out.
During the closing credits of the blooper episode, they show a clip of Kelly Coffield flubbing her line during a VM sketch. But we actually see it without the black-and-white effect. Her face is painted blue, and her costume and wig are also blue. It seems that this is similar to a blue-screen effect, only she acts as the blue screen (lol). They were able to remove the color from just her and project the added grain and scratches of an old movie onto her.
The full blooper episode is up on YouTube here: http://www.youtube.com/watch?v=TXTiFoEewhQ. Skip to 21:16 to see that clip.
Gene: "There's nothing wrong with Mother Nature."
Steve: "But it's not nice to fool with her."
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